
Advances and perspectives of spin coating techniques
- 1 Shanghai Ocean University, No.999, Huchenghuan Rd , Nanhui New City, Shanghai, P.R.
* Author to whom correspondence should be addressed.
Abstract
Spin coating is a kind of economically friendly technology accompanied by outstanding application performance, which has been widely adopted in the functional thin film fabrication field. Widespread attention has been attracted owing to their superior controllability. In this paper, the fundamental principles, film quality evaluation methods, and the current development of the spin coating technique are discussed. Through the ideal model and empirical formula, the key factors controlling the film thickness are obtained and are ready to produce marvelous functional films. Currently, the manufacturing demand for solar cells in the energy market is calling for high-quality thin films. Therefore, spin-coating has become a promising candidate. The characteristics of the spin-coating methods reviewed in this paper are adopted to maximize the properties of the obtained films and provide theoretical support for the preparation of high-efficiency solar cells. Finally, this novel growth point of using the spin coating method in the photovoltaic film is forecasted.
Keywords
spin coating, theoretical model, film quality evaluation, spin coating application
[1]. Sun Yuanyang. Frontiers of Materials Science, School of Materials Science and Engineering, North University of China. North University of China 1.
[2]. Wu Jiang, Xie Zhiyuan. 2012 Polymer thin film solar cells prepared by scratch coating method. Chinese Journal of Luminescence, 33(05): p. 540-544.
[3]. Xin Feng, et al., 2015 Comparison of preparation methods and application prospect of functional thin film materials. Journal of Ceramics, 36(03): p. 237-242.
[4]. Wang Dong, et al., 2012 Progress in preparation of functional thin films by spin coating. Imaging Science and Photochemistry, 30(02): p. 91-101.
[5]. Nisticò, R., D. Scalarone, and G. Magnacca, 2017 Sol-gel chemistry, templating and spin-coating deposition: A combined approach to control in a simple way the porosity of inorganic thin films/coatings. Microporous and Mesoporous Materials, 248: p. 18-29.
[6]. Panning, E.M., et al., 2016Novel detection and process improvement for organic coating-film defects, in Extreme Ultraviolet (EUV) Lithography VII.
[7]. CORPORATION, K. Spin Coating. 2022; Available from: https://www.keyence.com/ss/products/measure/sealing/coater-type/spin.jsp.
[8]. B.D.Washo, Li Qingrong. 1982 Rheological and model tests of spin coating process. Software Development, (02): p. 58-68.
[9]. Yue Hongda, Pan Longfa, Xu Duanyi. 2004 Volatilization and flow in dye spin coating process. Journal of Tsinghua University (Natural Science Edition), (02): p. 174-177.
[10]. Lai, C.-C. and F.-C. Chou, 2008 Effect of Relaxation Time on Spin Coating Instability. Japanese Journal of Applied Physics, 47(8): p. 6569-6573.
[11]. Mustafa, H.A.M. and D.A. Jameel, 2021 Modeling and the main stages of spin coating process: A review. Journal of Applied Science and Technology Trends, 2(03): p. 91-95.
[12]. Ge Zhongjiu, Li Mei, Zhang Zhishun, Feng Yuchen. 1996 Semiconductor heteroepitaxial thin films - determination of quality by X-ray diffraction. Chinese Journal of Luminescence, (03): p. 257-260.
[13]. Kaviyarasu, K., et al., 2017 Elucidation of photocatalysis, photoluminescence and antibacterial studies of ZnO thin films by spin coating method. J Photochem Photobiol B, 173: p. 466-475.
[14]. Tomulescu, A.G., et al., 2019 Reticulated Mesoporous TiO2 Scaffold, Fabricated by Spray Coating, for Large‐Area Perovskite Solar Cells. Energy Technology, 8(1).
[15]. Chaki, S.H., et al., 2017 Study of SnS2thin film deposited by spin coating technique. Materials Research Express, 4(7).
[16]. Yang Zhiyuan, Yang Jinshui. 2015 Application of scanning electron microscopy in the characterization of inorganic materials. Journal of Hubei Normal University (Natural Science Edition), 35(04): p. 56-63.
[17]. Wu, Y., et al., 2020 The preparation and study of multilayer structured SiO2–TiO2 film: the effects of photonic crystals on enhanced photocatalytic properties. Journal of Materials Science, 55(25): p. 11095-11105.
[18]. Zheng, J.-G., T. Aoki, and A. Paul, 2018 TEM Study of Epitaxial LSMO-BTO-STO Thin Film Heterostructures. Microscopy and Microanalysis, 24(S1): p. 2028-2029.
[19]. Rahong, S., et al., 2008 Synthesis of Carbon Nanofibers by Chemical Vapor Deposition Using Polyoxometalates as Catalysts. Sci. Special Issue on Nanotechnology, 7.
[20]. TwitterTRUSTe, L.F., A.c.-A.A. Site, and O.a.o.b. AZoNetwork. How to Characterize Thin Films. 2018 2018/3/19; Available from: https://www.azooptics.com/Article.aspx?ArticleID=1317#:~:text=Energy%20Dispersive%20Analysis%20of%20X-rays%20%28EDAX%20or%20EDS%29%2C,with%2C%20and%20incorporated%20into%2C%20SEM%20and%20TEM%20instruments.
[21]. Li, M., et al., 2020 Characterizing Interfacial Fracture Toughness Using AFM. Microscopy and Microanalysis, 6(S2): p. 722-723.
[22]. Bhandarkar, S.A., et al., 2021 Investigation of structural and optical properties of spin coated TiO2:Mn thin films. Optical Materials, 118.
[23]. Tammisola, O., et al., 2009 Spin coating of Blu-Ray disks: modeling, experiments, limitations, and manipulation. Journal of Coatings Technology and Research, 7(3): p. 315-323.
[24]. Takenaga, M., et al., 1983 TeOxthin films for an optical disc memory. Journal of Applied Physics, 54(9): p. 5376-5380.
[25]. Imaging, M. AR / AGAR Film - Mechanism and Effect. 2012; Available from: https://www.mecanusa.com/polarizer/AR-film/ARmechanism.htm.
[26]. Nho, H.W. and T.H. Yoon, 2017 Structural colour of unary and binary colloidal crystals probed by scanning transmission X-ray microscopy and optical microscopy. Sci Rep, 2017. 7(1): p. 12424.
[27]. Vyas, A., et al., 2021 Alkyl‐Amino Functionalized Reduced‐Graphene‐Oxide–heptadecan‐9‐amine‐Based Spin‐Coated Microsupercapacitors for On‐Chip Low Power Electronics. physica status solidi (b), 259(2).
[28]. Huang, J., S. Somu, and A. Busnaina, 2013 Spin coating fabrication of thin film transistors using enriched semiconducting SWNT solution. Electronic Materials Letters, 9(4): p. 505-507.
[29]. Wantana, K., et al., 2017 Study of thin film coating technique parameters for low cost organic solar cells fabrication. Materials Today: Proceedings, 4(5): p. 6626-6632.
[30]. N. Sadikin, S., 2017 Effect of Spin-Coating Cycle on the Properties of TiO2 Thin Film and Performance of DSSC. International Journal of Electrochemical Science, p. 5529-5538.
[31]. Primkulov, B.K., et al., 2020 Spin coating of capillary tubes. Journal of Fluid Mechanics, 886.
[32]. Liang, Y., et al., 2020 Fabrication of concave microlenses on a diamond by a spin coating process. Opt Express, 28(7): p. 9320-9326.
Cite this article
Yin,Y. (2023). Advances and perspectives of spin coating techniques. Applied and Computational Engineering,7,291-301.
Data availability
The datasets used and/or analyzed during the current study will be available from the authors upon reasonable request.
Disclaimer/Publisher's Note
The statements, opinions and data contained in all publications are solely those of the individual author(s) and contributor(s) and not of EWA Publishing and/or the editor(s). EWA Publishing and/or the editor(s) disclaim responsibility for any injury to people or property resulting from any ideas, methods, instructions or products referred to in the content.
About volume
Volume title: Proceedings of the 3rd International Conference on Materials Chemistry and Environmental Engineering (CONF-MCEE 2023), Part II
© 2024 by the author(s). Licensee EWA Publishing, Oxford, UK. This article is an open access article distributed under the terms and
conditions of the Creative Commons Attribution (CC BY) license. Authors who
publish this series agree to the following terms:
1. Authors retain copyright and grant the series right of first publication with the work simultaneously licensed under a Creative Commons
Attribution License that allows others to share the work with an acknowledgment of the work's authorship and initial publication in this
series.
2. Authors are able to enter into separate, additional contractual arrangements for the non-exclusive distribution of the series's published
version of the work (e.g., post it to an institutional repository or publish it in a book), with an acknowledgment of its initial
publication in this series.
3. Authors are permitted and encouraged to post their work online (e.g., in institutional repositories or on their website) prior to and
during the submission process, as it can lead to productive exchanges, as well as earlier and greater citation of published work (See
Open access policy for details).