The influence and mechanism of transition metal ions dissolution in lithium-ion batteries

Research Article
Open access

The influence and mechanism of transition metal ions dissolution in lithium-ion batteries

Zhaohua Zhang 1*
  • 1 The University of New South Wales    
  • *corresponding author lhenry84250@student.napavalley.edu
Published on 7 November 2023 | https://doi.org/10.54254/2755-2721/26/20230829
ACE Vol.26
ISSN (Print): 2755-273X
ISSN (Online): 2755-2721
ISBN (Print): 978-1-83558-073-8
ISBN (Online): 978-1-83558-074-5

Abstract

Lithium-ion battery (LIB) has been extensively applied in the field of power vehicles and energy storage. Extending the service life is the research priority. Transition metal (TM) ions dissolved from the cathode are considered a key factor affecting battery electrochemical properties. To reveal comprehensively the mechanisms of influence of TM ions at the full-cell level, this paper reviews the recent efforts of the exploration of TM ions affecting lithium-ion batteries using conventional metal oxide as cathode matched with graphite, silicon-containing, or Li metal as anode, respectively. The existence of TM ions in electrolyte or solid electrolyte interphase (SEI) films can change the morphology, the structure as well as the component concentration of the SEI films and accelerate the side reaction as a catalyst. In the comparison of different TM ions, the failure mechanism could be diverse, and it is proved that Mn ion is the most detrimental and extensively studied. However, in some special lithium-ion battery systems, TM ions are even in favour of electrochemical performance by forming LiF-rich SEI components.

Keywords:

lithium-ion battery, transition metal dissolution, crosstalk

Zhang,Z. (2023). The influence and mechanism of transition metal ions dissolution in lithium-ion batteries. Applied and Computational Engineering,26,186-192.
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References

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[13]. Kim M, Yang Z, Trask S E, et al. 2022 ACS Applied Materials & Interfaces, 14(13): 15103-15111.

[14]. Kim M, Harvey S P, Huey Z, et al. 2023Energy Storage Materials, 55: 436-444.

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[18]. Tan S, Kim J M, Corrao A, et al. 2023 Nature Nanotechnology, 18(3): 243-249.


Cite this article

Zhang,Z. (2023). The influence and mechanism of transition metal ions dissolution in lithium-ion batteries. Applied and Computational Engineering,26,186-192.

Data availability

The datasets used and/or analyzed during the current study will be available from the authors upon reasonable request.

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About volume

Volume title: Proceedings of the 2023 International Conference on Functional Materials and Civil Engineering

ISBN:978-1-83558-073-8(Print) / 978-1-83558-074-5(Online)
Editor:Bhupesh Kumar
Conference website: https://www.conffmce.org/
Conference date: 26 August 2023
Series: Applied and Computational Engineering
Volume number: Vol.26
ISSN:2755-2721(Print) / 2755-273X(Online)

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References

[1]. Tarascon J M, McKinnon W R, Coowar F, et al. 1994 Journal of The Electrochemical Society, 141(6): 1421.

[2]. Gallus D R, Schmitz R, Wagner R, et al. 2014 Electrochimica Acta, 134: 393-398.

[3]. Shkrob I A, Kropf A J, Marin T W, et al. 2014 The Journal of Physical Chemistry C, 118(42): 24335-24348.

[4]. Jung R, Linsenmann F, Thomas R, et al. 2019 Journal of the electrochemical society, 166(2): A378-A389.

[5]. Wandt J, Freiberg A, Thomas R, et al. 2016 Journal of Materials Chemistry A, 4(47): 18300-18305.

[6]. Metzger M, Marino C, Sicklinger J, et al. 2015 Journal of The Electrochemical Society, 162(7): A1123.

[7]. Solchenbach S, Hong G, Freiberg A T S, et al. 2018Journal of The Electrochemical Society, 165(14): A3304-A3312.

[8]. Joshi T, Eom K S, Yushin G, et al. 2014 Journal of the electrochemical society, 161(12): A1915.

[9]. Wang C, Xing L, Vatamanu J, et al. 2019Nature communications, 10(1): 3423.

[10]. Banerjee A, Shilina Y, Ziv B, et al. 2017 Journal of the American Chemical Society, 139(5): 1738-1741.

[11]. Cui X, Sun J, Zhao D, et al. 2023 Journal of Energy Chemistry, 78: 381-392.

[12]. Zhang X, Cui Z, Manthiram A. 2022 Advanced Energy Materials, 12(14): 2103611.

[13]. Kim M, Yang Z, Trask S E, et al. 2022 ACS Applied Materials & Interfaces, 14(13): 15103-15111.

[14]. Kim M, Harvey S P, Huey Z, et al. 2023Energy Storage Materials, 55: 436-444.

[15]. Langdon J, Manthiram A. 2021Advanced Functional Materials, 31(17): 2010267.

[16]. Li W, Jie Y, Chen Y, et al. 2022Nano Research, 2022: 1-8.

[17]. Betz J, Brinkmann J P, Nölle R, et al. 2019Advanced energy materials, 9(21): 1900574.

[18]. Tan S, Kim J M, Corrao A, et al. 2023 Nature Nanotechnology, 18(3): 243-249.